Tuneable Red and Blue Emission of Bi³⁺-Co-Doped SrF₂:Eu³⁺ Nanophosphors for LEDs in Agricultural Applications

Abstract

Tunable blue/red dual-emitting Eu3+-doped, Bi3+-sensitized SrF2 phosphors were synthesized utilizing a solvothermal-microwave method. All phosphors have cubic structure (Fm-3m (225) space group) and well-distinct sphere-like particles with a size of ~20 nm, as examined by X-ray diffraction and transmission electron microscopy. The diffuse reflectance spectra reveal a redshift of the absorption band in the UV region as the Bi3+ concentration in SrF2: Eu3+ phosphor increases. Under the 265 nm excitation, photoluminescence spectra show emission at around 400 nm from the host matrix and characteristic orange 5D0 → 7F1,2 and deep red 5D0 → 7F4 Eu3+ emissions. The red emission intensity increases with an increase in Bi3+ concentration up to 20 mol%, after which it decreases. The integrated intensity of Eu3+ red emission in the representative 20 mol% Bi3+ co-doped SrF2:10 mol% Eu3+ shows twice as bright emission compared to the Bi3+-free sample. To demonstrate the potential application in LEDs for artificial light-based plant factories, the powder with the highest emission intensity, SrF2: 10Eu, 20 Bi, was mixed with a ceramic binder and placed on top of a 275 nm UVC LED chip, showing pinkish violet light corresponding to blue (409 nm) and red (592, 614, and 700 nm) phosphors’ emission.

Keywords

• lanthanide luminescence
• phosphors
• LEDs for agricultural application
• Eu³⁺
• Bi³⁺