Química Nova (Jan 2009)

Produção de monoacilgliceróis e diacilgliceróis via glicerólise enzimática e destilação molecular Production of monoglycerides and diglycerides through lipase-catalyzed glycerolysis and molecular distillation

  • Patricia Bogalhos Lucente Fregolente,
  • Gláucia Maria F. Pinto,
  • Maria Regina Wolf-Maciel,
  • Rubens Maciel Filho,
  • César Benedito Batistella

DOI
https://doi.org/10.1590/S0100-40422009000600034
Journal volume & issue
Vol. 32, no. 6
pp. 1539 – 1543

Abstract

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Monoacilglycerides and diacilglycerides are produced through lipase-catalyzed glycerolysis of soybean oil using Candida antarctica B in a solvent-free system. The reaction was carried out at a glycerol to triacylglycerol molar ratio of 8:1 with 2% of lipase. Acylglycerides, free fatty acids (FFA) and glycerol produced were separated employing the molecular distillation process. Starting from a product of enzymatic reaction 25.06% of triacylglycerols, 46.63% of diacylglycerides, 21.72% of monoacylglycerides, 5.38% of FFA and 1.21% of glycerol and after consecutively distillations, monoacylglycerides with 80% of purity was obtained and also oil with 54% of diacylglycerides to be used in human dietary.

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