Ph3CCOOSnPh3.Ph3PO AND Ph3CCOOSnPh3.Ph3AsO: SYNTHESIS AND INFRARED STUDY

ABDOU MBAYE; ALEXIS BIENVENU BELEKE; CHEIKH ABDOUL KHADIR DIOP; LIBASSE DIOP

Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry (Aug 2014)

Ph3CCOOSnPh3.Ph3PO AND Ph3CCOOSnPh3.Ph3AsO: SYNTHESIS AND INFRARED STUDY

ABDOU MBAYE,
ALEXIS BIENVENU BELEKE,
CHEIKH ABDOUL KHADIR DIOP,
LIBASSE DIOP

Affiliations

ABDOU MBAYE: Université Cheikh Anta Diop Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
ALEXIS BIENVENU BELEKE: Université Cheikh Anta Diop Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
CHEIKH ABDOUL KHADIR DIOP: Université Cheikh Anta Diop Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
LIBASSE DIOP: Université Cheikh Anta Diop Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal

Journal volume & issue: Vol. 15, no. 2
pp. 185 – 187

Abstract

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The mixture of ethanolic solutions of Ph3CCOOSnPh3 and Ph3PO or Ph3AsO gives Ph3CCOOSnPh3.Ph3PO and Ph3CCOOSnPh3.Ph3AsO adducts which have been characterized by infrared spectroscopy. A discrete structure is suggested for both, the environment around the tin centre being trigonal bipyramidal, the triphenylacetate anion behaving as a mondentate ligand.

Published in Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry

ISSN: 1582-540X (Print)
Publisher: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
Country of publisher: Romania
LCC subjects: Technology: Chemical technology
Website: http://pubs.ub.ro/?pg=revues&rev=cscc6

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