NEW THIO S2- ADDUCTS WITH ANTIMONY (III AND V) HALIDE: SYNTHESIS AND INFRARED STUDY

Abstract

Five new S2- adducts with SbIII and SbV halides have been synthesized and studied by infrared. Discrete structures have been suggested, the environment around the antimony being tetrahedral, trigonal bipyramidal or octahedral.

Keywords

• S2 - polynuclear adducts
• SbIII
• SbV
• discrete structures
• S2- bridges
• sulfuration