Kinetics of Lignin Removal from Rice Husk Using Hydrogen Peroxide and Combined Hydrogen Peroxide–Aqueous Ammonia Pretreatments

Abstract

The rice husk has the potential to be used for converting agricultural wastes into renewable energy. Therefore, this study aims to improve the hydrolysis of rice husk through Hydrogen Peroxide (HP) and Combined Hydrogen Peroxide–Aqueous Ammonia (CHPA) pretreatments. The removal of lignin from rice husks was determined using SEM–EDS examination of the samples. At a specific concentration of H2O2, (CHPA) pretreatment eliminated a significantly larger amount of lignin from biomass. The percentage of lignin removal of HP varied from 48.25 to 66.50, while CHPA ranged from 72.22 to 85.73. Hence, the use of batch kinetics of lignin removal of both pretreatments is recommended, where the kinetic parameters are determined by fitting the experimental data. Based on the results, the activation energies for HP and CHPA pretreatments were 9.96 and 7.44 kJ/mol, which showed that the24 model is appropriate for the experimental data. The increase in temperatures also led to a higher pretreatment value, indicating their positive correlation. Meanwhile, CHPA pretreatment was subjected to enzymatic hydrolysis of 6% enzyme loading for the production of 6.58 g glucose/L at 25 h.

Keywords

• aqueous ammonia
• hydrogen peroxide
• lignin
• rice husk
• pretreatment
• kinetics