Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry (Feb 2015)

O2CC6H4C6H4CO2(SnPh3)2∙4H2O AND HO2CC6H4C6H4CO2SnBu2Cl: SYNTHESIS AND INFRARED STUDY

  • ABDOU MBAYE,
  • CHEIKH ABDOUL KHADIR DIOP,
  • LIBASSE DIOP

Journal volume & issue
Vol. 15, no. 4
pp. 357 – 360

Abstract

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When the diphenic acid HO2CC6H4C6H4CO2H is allowed to react with SnBu2Cl2 or SnPh3OH, HO2CC6H4C6H4CO2. SnBu2Cl (A) and O2CC6H4C6H4CO2(SnPh3)2∙4H2O(B) were obtained and characterized by infrared spectroscopy. The structures are an infinite chain or an oligomer, the diphenic anion being a monodentate or a monochelating ligand. The environment around the tin centers is trigonal bipyramidal or octahedral.

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