Adsorptive removal of Remazol Red (RR) from textile effluents using jute stick charcoal (JSC)

Abstract

The research aims to find out the reusability of jute stick charcoal (JSC) to remove Remazol Red (RR) from textile effluents. The JSC was characterized by scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, and Fourier-transform infrared (FTIR) spectroscopy to analyze the morphology, functional groups, and chemical composition, respectively. The batch adsorption method was applied in this study, and it disclosed that dye uptake depends on various factors, namely, pH, contact time, adsorbent dose, and dye concentration. Notably, 93.12% of the dye was removed with the best removal efficiency at a pH of 1, an adsorbent dose of 0.6 g, and an equilibrium time of 120 min, where the adsorption occurred rapidly in the first 20 min. The Langmuir isotherm model successfully defined the adsorption phenomena, yielding an R2 value of 0.995. The kinetic experimental data followed the pseudo-second-order model (R2 = 0.999). The optimum adsorption parameters were implemented for the effluent obtained from a dye bath where a fabric sample (5 g) was dyed with RR, and 62.4% dye was removed. For the scaled application of JSC to a wastewater stream, the raw textile effluent was also treated, which resulted in 52.6% of dye removal. These results show that JSC is a promising adsorbent for treating textile wastewater. HIGHLIGHTS Adsorption of RR dye on JSC and characterization of JSC were studied.; The adsorption process is highly pH-specific (pH = 1).; Nearly 93.12% of the dye removal was observed at optimized conditions.; The experimental findings fit well with pseudo-second-order and Langmuir models.; The optimum conditions have been implemented on both the dyed sample fabric bath (62.4% removal) and actual raw textile effluent (52.6%).;

Keywords

• adsorption
• isotherms
• jute stick charcoal
• kinetics
• remazol red (rr)
• textile wastewater