2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY

DAOUDA NDOYE; LIBASSE DIOP

Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry (Jan 2014)

2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY

DAOUDA NDOYE,
LIBASSE DIOP

Affiliations

DAOUDA NDOYE: Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
LIBASSE DIOP: Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal

Journal volume & issue: Vol. 14, no. 1
pp. 59 – 62

Abstract

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2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl and 2(Cy2NH2)2SO4. Sn(SO4)22Cy2NH2Cl complexes have been obtained on allowing Cy2NH2O2C-SO3H and Cy2NH2HSO4 to react respectively with SnBu2Cl2 and SnBu3Cl in specific ratios.The molecular structures of these compounds have been determined on the basis of the infrared data. The suggested structures are dimeric, the tin atom being octacoordinated by four chelating sulfate anions, the monomeric basic entities being connected by hydrogen bonded cation chloride cation strings.

Published in Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry

ISSN: 1582-540X (Print)
Publisher: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
Country of publisher: Romania
LCC subjects: Technology: Chemical technology
Website: http://pubs.ub.ro/?pg=revues&rev=cscc6

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