Analysis of Volatile Characteristic Flavors of Three Aroma Types of Shanzhuang Laojiu by Sensory Quantitative Descriptive Analysis and Gas Chromatography-Mass Spectrometry

Abstract

Sensory quantitative descriptive analysis (SQDA) was used to analyze the flavor structure of nine samples of three aroma types (Nongxiangxing, Jiang-flavor and Zhima-flavor) of Shanzhuang Laojiu, and the results showed that there were significant differences in flavor and taste attributes among the aroma types. Liquid-liquid extraction coupled with gas chromatography-mass spectrometry (LLE-GC-MS) was used to analyze the composition of volatile compounds in these samples, and a total of 74 volatile flavor compounds were identified at high concentrations, manly including esters, alcohols and acids. Based on their aroma activity values (OAVs), 10 characteristic compounds contributing to the aroma of Shanzhuang Laojiu were identified. Partial least squares (PLS) analysis and correlation analysis were used to study the correlation between the sensory attributes and the characteristic aroma compounds, and the results showed that the Jiang, Qu and empty-cup aromas all had good correlation with acetic acid; ethyl butyrate, ethyl caproate, ethyl octanoate, butyric acid and capric acid were the main flavor compounds responsible for the alcoholic, ester, grain-like, sweet and fruity aromas; and the caramel-like and burnt aromas were highly correlated with ethyl myristate, ethyl oleate, ethyl linoleate and 2,3-butanediol. This study may lay the foundation for future research of the flavor formation mechanism of the three aroma types of baijiu.

Keywords

• flavor characteristics; gas chromatography-mass spectrometry; sensory quantitative description analysis; odor activity value; partial least squares; shanzhuang laojiu