New Journal of Physics (Jan 2018)

Analysis of the crystal electric field parameters of YbNi4P2

  • Z Huesges,
  • K Kliemt,
  • C Krellner,
  • R Sarkar,
  • H-H Klauß,
  • C Geibel,
  • M Rotter,
  • P Novák,
  • J Kuneš,
  • O Stockert

DOI
https://doi.org/10.1088/1367-2630/aace35
Journal volume & issue
Vol. 20, no. 7
p. 073021

Abstract

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The crystal electric field (CEF) scheme of YbNi _4 P _2 is determined, based on experimental data from inelastic neutron scattering, heat capacity, susceptibility and NMR measurements. Despite the tetragonal crystal structure, 9 parameters are needed to describe the crystal field in YbNi _4 P _2 due to the orthorhombic site symmetry of the Yb ion. A large basal plane anisotropy is detected by the local probe NMR. Our analysis yields CEF excitation energies of 8.5, 12.5 and roughly 30 meV and a ground state wave function that is dominated by the $5/2$ state. Furthermore, we present an analysis of the CEF scheme based on density functional theory calculations, which confirms the large basal plane anisotropy.

Keywords