NEW ORGANOTIN (IV) FORMIATO ADDUCTS. SYNTHESIS AND SPECTROSCOPIC STUDIES

Abstract

Five new formiato complexes have been synthesized and studied by spectroscopic methods. The structures, when the cations are involved through hydrogen bonds, are supramolecular. The anion behaves as a monocoordinating ligand. The existence of tetrahedral SnBu2(HCO2)2 has been evidenced in this work.

Keywords

• formiato complexes
• IR
• Mössbauer
• monocoordinating ligand
• supramolecular structures
• tetrahedral SnBu2(HCO2)2