(Me4N)(NO2)2C6H3CO2 NEW MCl2 (M = Zn, Co, Cd) AND SnR3Cl (R = Me, Ph) ADDUCTS: SYNTHESIS AND INFRARED STUDY

BOCAR TRAORE; LIBASSE DIOP; MAMADOU SIDIBE

Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry (Jan 2014)

(Me4N)(NO2)2C6H3CO2 NEW MCl2 (M = Zn, Co, Cd) AND SnR3Cl (R = Me, Ph) ADDUCTS: SYNTHESIS AND INFRARED STUDY

BOCAR TRAORE ,
LIBASSE DIOP ,
MAMADOU SIDIBE

Affiliations

BOCAR TRAORE: Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
LIBASSE DIOP: Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
MAMADOU SIDIBE: Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal

Journal volume & issue: Vol. 14, no. 2
pp. 119 – 122

Abstract

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Five new (Me4N)(NO2)2C6H3CO2 adducts with MCl2 (M = Zn, Co, Cd) and SnR3Cl (R = Me, Ph) have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete, the anion behaving as mono- and bichelating ligand towards MX2, tri- and monodentate towards SnR3Cl (R = Me, Ph).The environment around Zn, Co and Cd is tetrahechal, while the tin (IV) centre is trigonal bipyramidal.

Published in Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry

ISSN: 1582-540X (Print)
Publisher: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
Country of publisher: Romania
LCC subjects: Technology: Chemical technology
Website: http://pubs.ub.ro/?pg=revues&rev=cscc6

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