(Me4N)(NO2)2C6H3CO2 NEW MCl2 (M = Zn, Co, Cd) AND SnR3Cl (R = Me, Ph) ADDUCTS: SYNTHESIS AND INFRARED STUDY
BOCAR TRAORE ,
LIBASSE DIOP ,
MAMADOU SIDIBE
Affiliations
BOCAR TRAORE
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
LIBASSE DIOP
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
MAMADOU SIDIBE
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
Five new (Me4N)(NO2)2C6H3CO2 adducts with MCl2 (M = Zn, Co, Cd) and SnR3Cl (R = Me, Ph) have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete, the anion behaving as mono- and bichelating ligand towards MX2, tri- and monodentate towards SnR3Cl (R = Me, Ph).The environment around Zn, Co and Cd is tetrahechal, while the tin (IV) centre is trigonal bipyramidal.
