CETONIZATION, DESARYLATION AND ESTERIFICATION IN THE INTERACTIONS BETWEEN PhPO3H2 AND SnPh3Cl: SYNTHESIS OF OC[OPOSnPh3OEt]2 AND INFRARED STUDY

MODOU SARR; AMINATA DIASSE-SARR; LIBASSE DIOP

Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry (Jul 2015)

CETONIZATION, DESARYLATION AND ESTERIFICATION IN THE INTERACTIONS BETWEEN PhPO3H2 AND SnPh3Cl: SYNTHESIS OF OC[OPOSnPh3OEt]2 AND INFRARED STUDY

MODOU SARR,
AMINATA DIASSE-SARR,
LIBASSE DIOP

Affiliations

MODOU SARR: Université Cheikh Anta Diop Faculté des Sciences et Techniques Département de chimie, Laboratoire de Chimie Minérale et Analytique, Dakar- SENEGAL
AMINATA DIASSE-SARR: Université Cheikh Anta Diop Faculté des Sciences et Techniques Département de chimie, Laboratoire de Chimie Minérale et Analytique, Dakar- SENEGAL
LIBASSE DIOP: Université Cheikh Anta Diop Faculté des Sciences et Techniques Département de chimie, Laboratoire de Chimie Minérale et Analytique, Dakar- SENEGAL

Journal volume & issue: Vol. 16, no. 2
pp. 185 – 188

Abstract

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On allowing PhPO3H2 to react with SnPh3Cl in ethanolic media, OC[OPOSnPh3OEt]2 is obtained by cetonization, desarylation and esterification, has been studied by infrared technic. A discrete structure has been suggested on the basis of infrared data, the anion behaving as a bidentate ligand, the environment around the tin centres being tertrahedral.

Published in Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry

ISSN: 1582-540X (Print)
Publisher: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
Country of publisher: Romania
LCC subjects: Technology: Chemical technology
Website: http://pubs.ub.ro/?pg=revues&rev=cscc6

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