In Situ Validation Methodology for Weighing Methods Used in Preparing of Standardized Sources for Radionuclide Metrology

Abstract

High-accuracy source standards preparation in radionuclide metrology is based on a properly described and reliable weighing procedure able to achieve relative standard uncertainties below 0.1%. However, the results of uncertainty budget comparison CCRI(II)-S7 put in check the ability of the former pycnometer and substitution weighing methods to attain this goal. As a result, a question arises about the validation of mass measurements performed from the elimination weighing method when appropriate uncertainties are required. In order to address this problem, a comprehensive in situ validation methodology is proposed for the results of the pycnometer, substitution, elimination and modified elimination (MEM) methods. Mass comparisons are applied to evaluate the compatibility between weighing methods’ results. It is possible due to a developed weighing sequence, which allows for the performing of all methods by only one drop deposition in the range of mass from 10 mg to 200 mg. As a result, the high degree of compatibility between the MEM and elimination method for uncertainties below 0.1% has been achieved, as well as for higher uncertainties to pycnometer and substitution methods. Numerical simulations indicate that the validation results remain valid on improved technical implementations for these last two methods.

Keywords

• radionuclide metrology
• source preparation
• weighing methods
• modified elimination method
• measurement uncertainty evaluation