南方能源建设 (Sep 2024)

Research Progress of Pressure Swing Adsorption CO2 Capture Technology and Case Analysis of Its Application in Petrochemical Industry

  • Qiang LIU,
  • Jin XIAO,
  • Hang YU,
  • Haizhong LUO,
  • Qingyang HE,
  • Haizhou LIN,
  • Rong XUE

DOI
https://doi.org/10.16516/j.ceec.2024.5.04
Journal volume & issue
Vol. 11, no. 5
pp. 37 – 49

Abstract

Read online

[Introduction] As an important carbon capture method in CCUS, pressure swing adsorption (PSA) CO2 capture technology has been widely used. However, the excessive capture energy consumption and operation cost restrict the promotion and implementation of the technology. How to accurately select the appropriate capture technology according to the actual situation and reduce the capture energy consumption is particularly important. [Method] This paper discussed the basic research and technical application of PSA technology at home and abroad, and analyzed the economy and prospect of PSA technology in petrochemical industry based on a practical application case of PSA technology for CO2 capture in a petrochemical enterprise.[Result] In this case, the project using PSA CO2 capture technology captured and stored about 800000 tons of medium-concentration carbon sources produced by the purification unit and low-temperature methanol washing unit of the coal-to-hydrogen plant. For 73.9% concentration of CO2 raw gas, the device achieved 96% CO2 recovery rate and 98% capture purity. H2S, CH4 and CH3OH are all controlled below 0.015%, which can achieve about 56 kWh/t CO2 capture power consumption. It is found that pressure swing adsorption technology has the advantages of low energy consumption, low piezoresistivity, continuous process and strong stability of adsorbent, which shows the technical and economic feasibility. Since pressure swing adsorption is mainly physical adsorption, PSA may face the problem of high energy consumption and insufficient enrichment concentration for the treatment of low concentration of CO2 feed gas. [Conclusion] In summary, PSA CO2 capture technology is suitable for the treatment of medium concentration carbon sources, and has potential in thetreatment of exhaust emissions in petrochemical, cement and other industries in the future.

Keywords