Independence of optical absorption on Auger ionization in single-walled carbon nanotubes revealed by ultrafast e–h photodoping

Abstract

Auger-ionized free-carriers in a one-dimensional semiconductor are predicted to result in a strong band-gap renormalization. Isolated single-walled carbon nanotubes (SWCNT) under high-intensity laser irradiation exhibit strong nonlinear photoluminescence (PL) due to exciton–exciton annihilation (EEA). The presence of exciton disassociation during the rapid Auger-ionization caused by EEA would lead to a strong nonlinear absorption. By simultaneously measuring SWCNT–PL and optical absorption of isolated SWCNT clusters in the PL saturation regime, we give evidence that Auger-ionized excitons do not disassociate but remain bound.

Keywords

• carbon nanotube
• photoluminescence
• optical absorption
• Auger ionization
• free-carrier generation
• single-walled carbon nanotube