Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry (Jul 2010)
NEW ORGANOTIN (IV) HETEROPOLYNUCLEAR COMPLEXES CONTAINING [SnPh[sub]2[/sub]Cl[sub]2[/sub]X][sub][sup]- [/sup][/sub](X = Cl, Br): SYNTHESIS AND SPECTROSCOPIC STUDIES
Abstract
Four [SnPh[sub]2[/sub]Cl[sub]2[/sub]X][sup]-[/sup] (X = Cl, Br) containing complexes with metal complexes adverse cations have been synthesized and studied by infrared and Mössbauer spectroscopy. The suggested structures are ionic, SnPh[sub]2[/sub]Cl[sub]2[/sub]X[sup]-[/sup] as mononuclear, a binuclear or a trinuclear anion being in electrostatic interactions with the metal complex cation.